The advance of chiral phosphate-ester( phosphonate-ester)[ phosphoramides( phosphonyl-amide)] in asymmetric alkylation reaction, Aldol reaction, hydrogenation reaction, cyanosilylation reaction was reviewed with48 references. 讨论了手性膦()胺及膦()酯催化剂在不对称烷基化、对称缩合、对称氢化、对称氰矽化等反应中应用的最新研究进展。参考文献48篇。
aldol
[ noun ] an oily colorless liquid obtained by the condensation of two molecules of acetaldehyde; contains an alcohol group (-OH) and an aldehyde group (-CHO) <noun.substance>
Aldol \Al"dol\, n. [Aldehyde + -ol as in alcohol.] (Chem.) A colorless liquid, {C4H8O2}, obtained by condensation of two molecules of acetaldehyde: CH3CHO + CH3CHO = H3CH(OH)CH2CO; also, any of various derivatives of this. The same reaction has been applied, under the name of
{aldol condensation}, to the production of many compounds. [Webster 1913 Suppl.]